(Alkali) Surfactant Polymer


Alkaline-Free Surfactant Polymer Process for Heavy Oil

S. Hocine (Solvay) | A. Magnan (Solvay) | G. Degre (Solvay) | N. Rousseau (IFP Energies nouvelles) | D. Rousseau (IFP Energies nouvelles)



Chemical EOR methods have become an increasingly attractive option for heavy oil reservoirs where thermal methods (such as SAGD) cannot be applied, like in thin reservoirs. Polymer flooding in heavy oil recently proved to be a viable recovery method. The use of surfactants for heavy oil is reported only in a limited number of cases and mostly in combination with alkali to benefit from the generation of in-situ surfactants. However, operational issues (such as scale or corrosion) associated to the use of alkali as well as negative impacts on project logistics are often reported. Objective of this work is to demonstrate at lab scale the efficiency of alkali-free surfactant/polymer process in the context of heavy oil reservoirs.


The present investigation is focused on a Canadian heavy-oil (14°API and 1400 cP) in representative reservoir conditions (high permeability sandstone, temperature of 35°C, low salinity). A dedicated synthetic surfactant formulation is designed using a screening methodology based on a robotic platform. Ultra-low interfacial tensions are evidenced from phase behavior and confirmed by spinning-drop tensiometry. Oil recovery performances of the surfactant formulation are then evaluated in corefloods.


Cores at Swi are first polymer flooded until no oil is produced to reach a residual oil saturation. A surfactant-polymer formulation is then injected after the polymer flood. Results show that additional oil is produced as a continuous oil bank, corresponding to 90% ROIP. This indicates that the surfactant is able to mobilize most of the residual oil. The results of this exploratory investigation show that alkaline-free surfactant-polymer processes could be applied to heavy oil reservoirs while minimizing operational issues. Complementary work will also be presented on optimization of the process including injection strategy improvement and surfactant dosage reduction.

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